From your comment, it's hard to infer that the poor result you got was due to the higher sample rate. However, every thing else being equal, the rule to follow with SPEC is that the higher the sample rate, the larger the FFT window size should be. In Plogue, set the FFT size to 16384, which is the maximum size. Then, in SPEC, reset the FFT latency. With this FFT window size, the DSP load will be quite high. If you want to live monitor before running the album (you should if you want to avoid unpleasant surprises), you may have to temporarily bypass some parts of the layout (like AutoV2, if you are using it). Make sure to set them back to Processing before running the album through in offline mode.
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